网状季胺基阴离子吸附剂制备及吸附性能

以丝瓜络为原料,采用醚化-接枝技术制备出季胺基阴离子交换吸附剂。采用电镜扫描、傅里叶红外光谱、比表面积孔径分布测定仪和元素分析仪等仪器对其进行分析和结构表征,并考察了温度、p H和硝酸盐初始浓度等因素对NO-3去除率的影响。实验结果表明,在20℃,p H值为3~10时,NO-3的吸附率可达90%左右;在不同温度下该吸附过程用Langmuir等温线模型和Freundich等温线模型描述均可;与伪一级动力学方程相比,伪二级动力学方程能更好地描述其吸附动力学方程。     

Effects of rare earth elements on the distribution of mineral elements and heavy metals in horseradish

In order to investigate the effects of rare earth elements (REEs) on horseradish, the distribution of the mineral elements and heavy metals in different organs of horseradish have been studied by using inductively coupled plasma-atomic emission spectrometry (ICP-AES). Meanwhile, three variable major parameters, namely the concentration of REEs, the type of REEs, and the growth stage of plant were chosen. The results indicated that the test REEs, Ce(III) and Tb(III), could be accumulated in leaves, stems and roots of horseradish. In addition, we found that the content of mineral elements was increased in horseradish treated with 20mgl(-1) of Ce(III), but not those with the 20mgl(-1) of Tb(III). Moreover, the content of mineral elements in horseradish was decreased with the increasing concentration of REEs (100, 300mgl(-1)). Furthermore, we found that there were the opposite effects on the content of the heavy metals in horseradish treated with REEs. Finally, we found that the effect of REEs on the accumulation of REEs, and the content of mineral elements or heavy metals of horseradish during vigorous growth stage, no matter positive or negative, was more obvious than that of the other growth stages. These results demonstrated that the distribution behaviors of mineral elements and heavy metals in horseradish can be affected by the type and concentration of REEs, and the growth period of plant.     

Coincidence and Upgrade： A Typical Case Study of Rural Ecotourism Development

At present, internal rural tourism is at the stage of upgrading and renewing, and ecotourism has been considered to be the main direction. This paper discussed the concepts and criteria of rural tourism and ecotourism, analyzed a typical case of Nongke Village of Chengdu City-being considered to be the first rural tourism site in China, went deep into the problems of the contents and criteria of the development of rural ecotourism, and tried to probe into the principles of the development of rural ecotourism both theoretically and practically so as to understand the rules of the development of rural ecotourism .     

Ambient air monitoring of PCDD/Fs and co-PCBs in Gyeonggi-do, Korea

We started the monitoring for PCDD/Fs in ambient air and soil in August 2001, and co-PCBs in January 2002. Decreasing of PCDD/Fs and co-PCBs levels in ambient air were observed. The higher PCDD/Fs levels were found in winter and lower in autumn. We found that the industrial incinerators influenced the PCDD/Fs levels in ambient air. In the 2,3,7,8-substituted PCDD/Fs concentration profiles, the three major congeners occupied 67% of the total mass. In case of co-PCBs, PCB#118, #105 and #77 were observed as the main congeners. Five cluster groups discriminated by ratio of four components, O(8)CDD, 1,2,3,4,6,7,8-H(7)CDD, 1,2,3,4,6,7,8-H(7)CDF and O(8)CDF, were obtained from HCA (hierarchical cluster analysis).     

中小企业化学品职业危害预防控制指南

为了帮助中小企业控制预防控制化学品职业危害,本文详细介绍了国际劳工组织所推行的中小企业化学品职业危害控制指南,包括化学职业卫生管理的主要内容和基本步骤,关键点危险区的确定方法,改进化学品职业危害管理、实施化学品管理的良好规范、制定化学品管理行动计划和编制全面的化学品清单等方法,以达到系统提高化学品管理水平和持续改进的目标和要求.     

Fenton法氧化处理水中土霉素的研究

为了评价Fenton法预处理抗生素生产废水中残留的高浓度土霉素的可行性,对Fenton试剂(Fe2 -H2O2)法催化氧化降解水溶液中的土霉素进行了研究.探讨了H2O2与Fe2 投加比例、投加量以及起始pH值对降解效果的影响,同时考察了土霉素废水中大量共存的草酸根离子对氧化过程的影响.结果表明,当H2O2与Fe2 按照5:1的比例投加时降解效率最高,最佳初始pH值在3.0-4.0之间.在最佳投加比例下,H2O2投加量为0.9 mmol/L,100 mg/L的土霉素可在10 min内得到完全降解.最佳反应条件下经过处理后土霉素水溶液TOC的去除率达40%左右,可生化性(BOD5/COD)也得到明显的改善.水中共存的草酸根离子对氧化效率具有明显的影响,但通过增加亚铁离子的量可以消除草酸的影响.     

长江河口近岸水体自然净化作用及其初步评价

按照水体的净化机理，结合长江口和上海滨岸带近岸水体的物理、化学和生物等因素的实际特征，对近岸水体的自然净化作用进行了阐述和分析。并在历史资料和实测资料基础上，就近岸水体的自然净化作用进行了评价。评价结果表明，因长江河口近岸水体存在较强的自然净化作用机制，近岸水体体的自然净化能力较强，环境容量较大，但由于污染物输入量的不断增加，部分岸段近岸水体的环境质量有逐渐下降的趋势；近岸水体的自然净化作用具有明显的季节性变化，长江口南岸水域洪水季节水体的自然净化作用比估水季节强，而杭州湾北岸水域的自然净化作用表现为相反的变化趋势，因此建议在近岸污水排放过程中应考虑近岸水体的净化能力，遵循水体的自然净化作用规律。     

湖北省雨涝灾害的风险评估与区划

随着我国灾害科学研究的不断深入及经济建设的日益发展，从风险角度分析灾害已成为灾害分析的一种新视角，它有助于决策者进行灾害管理和制定减灾策略时有针对性地选择最优技术政策，防患于末然。雨涝灾害是湖北省最严重的气象灾害之一，据统计，湖北省平均每年受雨涝危害的农田面积为80．62万hm^2，成灾面积为47．07万hm^2，特别是20世纪80年代以来湖北省工农业生产重地江汉平原和鄂东雨涝事件明显增多，严重威胁和制约着我省国民经济持续稳定发展。依据自然灾害风险分析原理，在分析湖北省雨涝灾害孕灾环境、致灾因子、承灾体密度和经济发展水平及承灾体的抗灾能力的基础上，综合评价了湖北省雨涝灾害风险程度的地域差异，以能综合体现风险程度的风险指数作为指标，将湖北省雨涝灾害分为极重度、重度、中度和轻度四个风险区，并提出了相应的对策措施，为有关部门灾害管理和减灾决策制定提供了参考依据。     

污水灌溉风险概率分布的研究

针对目前我国水资源紧缺、用大量污水进行农田灌溉造成环境污染的现状,指出了污水灌溉风险研究中的不足.利用农业干旱模型,通过非参数检验对污水灌溉风险的概率分布进行了研究,并利用江苏省南京地区某污灌区的实际资料,计算了当地污水灌溉风险的概率分布.